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22 CH203 Fall 2014 Lecture 22 October 24.pdf

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CP203 LecLure 22 CcLober 24, 2014 Allyllc halogenauon 8adlcal auLoxldauon 8ancldlñcauon 2 ! # $ % & (#)*+, *,,$-. )/# 0 1 2 !! , 34,$ 0 56 17 ! 8 0562 ! 8 2561 ! 8 9 # #$%& ,4 )*+:)+, ;/#? , / //#? @ // ! 8 ()/# -#/#$=. . % /$) .+, /)/# 1he allyl radlcal 4 8eacuon of a sLable-lsoLope labeled propene under radlcal bromlnauon condluons glves an equal mlxLure of Lhe Lwo posslble producLs
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  ! #$% '()*+,( ## -)*./(, #01 #$20 344546) 784.9(:8;.: <8=6)84 8+*.>6=8;.: <8:)6=6?)8;.: #     !       #   $   %   & (#)*+, *,,$-. )/# 0 1 2 !  , 34,$ 0 56 17     8   0562   8 2561   8  9 # #$%& ,4 )*+:)+, ;<# $)/#5-#/#$=. . % >/#? , /<# @)& 4$,= 0 /, 1 .> /<# >/#? @<.*< <)> /<# A)$%#>/   8   ()/# -#/#$=. . % /$) >.+, >/)/#    @7( 84454 ,8=6)84 0 <(8);.: .A 8 B*8/4(C6B.*.D( 48/(4(= D,.D(:( +:=(, ,8=6)84 /,.E6:8;.: ).:=6;.:B 96F(B 8: (G+84 E6>*+,( .A *7( *H. D.BB6/4( D,.=+)*B .A /,.E6:8;.: 8* *7( (:= )8,/.:BI J. D,.=+)* A,.E /,.E6:8;.: 8* *7( E6==4( )8,/.: 6B ./B(,F(=I K75L H 2 CHC 13 CH 3 [1- 13 C]Propene CH 2 HC 13 CH 2  H 2 CHC 13 CH 2 Br Br + Br 2 H 3 CC 13 CH 2 Br M$NM$
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